目次
總序 i
前言 iii
第 1部分化 學(xué) 原 理Part 1Chemical Principles
第1章 氣體、液體和溶液的性質(zhì) 3
Chapter 1 The Behaviors of Gas,Liquid and Solution 3
1.1 氣體的性質(zhì) 3
The Properties of Gases 3
1.2 液體17
Liquids 17
1.3 溶液23
Solutions 23
第2章 化學(xué)熱力學(xué)基礎(chǔ)與化學(xué)平衡 38
Chapter 2 The Basis of Chemical Thermodynamics and Chemical
Equilibrium38
2.1 化學(xué)熱力學(xué)的體系與狀態(tài)38
System and State of Chemical Thermodynamics 38
2.2 熱力學(xué)第一定律42
First Law of Thermodynamics 42
2.3 熱化學(xué)47
Thermochemistry 47
2.4 熱力學(xué)第二定律51
無機(jī) 化 學(xué)
Second Law of Thermodynamics 51
2.5 化學(xué)平衡61
Chemical Equilibrium 61
第3章 酸堿理論與電離平衡 71
Chapter 3 The Theories of Acids & Bases and lonization Equilibrium71
3.1 酸堿理論71
The Theories of Acids and Bases 71
3.2 弱酸弱堿的電離平衡77
The lonic Equilibrium of Weak Acids and Weak Bases 77
3.3 鹽的水解89
The Hydrolysis of Salts 89
第4章 沉淀反應(yīng) 92
Chapter 4 The Precipitation Reactions 92
4.1 溶度積92
Solubility Product 92
4.2 沉淀-溶解平衡的移動(dòng) 95
Equilibrium Shift between Precipitation and Dissolution 95
4.3 多種沉淀之間的平衡97
Equilibrium in Many Precipitants 97
第5章 氧化-還原反應(yīng)和電化學(xué) 104
Chapter 5 Oxidation-Reduction Reaction and Electrochemistry 104
5.1 氧化-還原反應(yīng)104
Oxidation-Reduction Reaction 104
5.2 電極電勢 111
Electrode Potential 111
5.3 電極電勢的應(yīng)用 124
Applications of Electrode Potential 124
第6章 化學(xué)動(dòng)力學(xué)基礎(chǔ)131
Chapter 6 The Basis of Chemical Dynamics 131
6.1 化學(xué)反應(yīng)速率 131
The Rate of Chemical Reaction 131
6.2 化學(xué)反應(yīng)機(jī)理 154
Reaction Mechanism 154
目次
第2部分 化 學(xué) 理 論
Part 2Chemical Theories
第7章 原子結(jié)構(gòu)和元素周期律163
Chapter 7 The Atomic Structure and Periodic System of Elements 163
7.1 原子內(nèi)部的發(fā)現(xiàn) 164
Discovery of Structure in Atom 164
7.2 氫原子光譜和能級(jí)的概念 170
The Spectrum of Atomic Hydrogen and Concept of Energy Levels
170
7.3 原子核外電子的運(yùn)動(dòng)狀態(tài) 177
Moving Stations of Electrons outer the Atomic Nucleus 177
7.4 多電子原子結(jié)構(gòu)和周期系 185
Structure in Many-Electron Atoms and Periodic System 185
7.5 元素基本性質(zhì)的周期性 195
Periodic Properties of the Elements 195
第8章 化學(xué)鍵和分子、晶體結(jié)構(gòu) 202
Chapter 8 Chemical Bonds and Structures of Molecules & Crystals 202
8.1 共價(jià)鍵與分子幾何構(gòu)型 202
Covalent Bond and Molecular Geometric Structure 202
8.2 金屬鍵與金屬晶體 232
Metallic Bond and Metallic Crystal232
8.3 離子鍵與離子晶體 243
lonic Bond and lonic Crystal 243
8.4 晶體學(xué)基礎(chǔ) 257
Basic Crystallology 257
第9章 配位化合物267
Chapter 9 The Coordination Compounds 267
9.1 配合物的基本概念 268
Basic Concepts of Coordination Compounds 268
9.2 配位化合物的異構(gòu)現(xiàn)象 279
無機(jī) 化 學(xué)
Isomerism of Coordination Compounds 279
9.3 配合物的化學(xué)鍵理論 298
The Chemical Bond Theories of Complexes 298
9.4 配位平衡及配合物的穩(wěn)定性 315
Coordination Equilibrium and Stabilization of Complex 315
9.5 配位化合物的應(yīng)用 322
Application of Coordination Compounds 322
第3部分描 述 化 學(xué)
Part 3 Descriptive Chemistry
s區(qū)和 p區(qū)元素化學(xué)引言 331
Introduction of the Chemistry of s and p Elements 331
第10章 稀有氣體 334
Chapter 10 The Rare Gases 334
10.1 稀有氣體的通性334
General Properties of Rare Gases 334
10.2 氙的化學(xué)338
Chemistry of Xenon 338
第11章 氫、堿金屬和堿土金屬345
Chapter 11 Hydrogen, Alkali and Alkali-earth Metals 345
11.1 氫及其化合物345
Hydrogen and Its Compounds 345
11.2 堿金屬元素及其化合物351
Alkali Metals and Their Compounds 351
11.3 堿土金屬及其化合物358
Alkali-earth Metals and Their Compounds 358
11.4 專題討論366
Discussion of Special Subjects 366
第 12章 鹵素 369
Chapter 12 The Halogens 369
12.1 氟及其化合物370
目次
Fluorine and Its Compounds 370
12.2 氯及其化合物374
Chlorine and Its Compounds 374
12.3 溴分族380
Bromine Subgroup 380
12.4 擬鹵素和擬鹵化物386
Pseudohalogen and Pseudohalide 386
第13章 氧族元素 390
Chapter 13 The Oxygen Family Elements 390
13.1 氧及其化合物391
Oxygen and Its Compounds 391
13.2 硫及其化合物398
Sulfur and Its Compounds 398
13.3 硒分族407
The Selenium Subgroup 407
第14章 氮族元素 412
Chapter 14 The Nitrogen Family Elements 412
14.1 氮及其化合物413
Nitrogen and Its Compounds 413
14.2 磷及其化合物423
Phosphorus and Its Compounds 423
14.3 砷分族430
The Arsenic Subgroup 430
第 15 章 碳族元素 436
Chapter 15 The Carbon Family Elements 436
15.1 碳及其化合物437
Carbon and Its Compounds 437
15.2 硅及其化合物445
Silicon and Its Compounds 445
15.3 鍺分族450
The Germanium Subgroup 450
第16章 硼族元素 455
Chapter 16 The Boron Family Elements 455
無 機(jī) 化 學(xué)
16.1 硼及其化合物456
Boron and Its Compounds 456
16.2 鋁及其化合物466
Aluminum and Its Compounds 466
16.3 鎵分族470
Gallium Subgroup 470
16.4 鹽的水解的討論474
Discussion of Salt Hydrolysis 474
第17章 銅、鋅分族476
Chapter 17 The Copper Subgroup and Zinc Subgroup 476
17.1 銅分族476
The Copper Subgroup 476
17.2 鋅分族484
The Zinc Subgroup 484
第18章 過渡元素(I)492
Chapter 18 The Transition Elements(I) 492
18.1 鈦分族495
The Titanium Subgroup 495
18.2 釩分族502
The Vanadium Subgroup502
18.3 鉻分族507
The Chromium Subgroup 507
18.4 錳分族516
The Manganese Subgroup 516
第19章 過渡元素(Ⅱ) 526
Chapter 19 The Transition Elements(Ⅱ) 526
19.1 鐵系元素526
The Ferrous Elements 526
19.2 鉑系元素538
The Platinum Elements 538
第20章 鑭系元素和鋼系元素 545
Chapter 20 The Lanthanides and Actinides 545
20.1 鑭系元素545
目次
The Lanthanides 545
20.2 銅系元素560
The Actinites 560
Appendix1 An Element Crossword 568
Appendix 2 Thermodynamic Properties of Some Selected Inorganic
Compounds 572
Appendix 3 Standard Half-Cell Reduction Potentials of Selected
Elements 589
Appendix 4 Charge Densities of Selected lons 593
Appendix 5 Selected Bond Energies 596
Appendix 6 Ionization Energies of Selected Metals 598
Appendix 7 Electron Affinities of Selected Nonmetals 600
Appendix 8 Electronegativities of Selected Elements 601
Appendix 9 Selected Lattice Energies 602
Appendix 10 Selected Hydration Enthalpies 603
Appendix 11 Selected Ionic Radii 604
Appendix 12 Vapor Pressure of Water at Various Temperatures 605
Appendix 13 Boiling Point Elevation and Freezing Point Depression
Constants 606
Appendix 14 Enthalpies of Combustion for Some Selected OrganicCompounds 607
Appendix 15Dissociation Constants of Weak Acids and Bases 608
Appendix 16 Solubility Product Constants of Selected Slightly Electrolytes 609
Appendix 17 Formation Constants of Some Selected Complex lons in
Aqueous Solution 610
Appendix 18 Physical and Chemical Constants 611
元素周期表612